Bài 1:

\(a.n_{NaOH\left(tổng\right)}=0,05.1+0,2.0,2=0,09\left(mol\right)\\ V_{ddNaOH\left(tổng\right)}=50+200=250\left(ml\right)=0,25\left(l\right)\\ C_{MddNaOH\left(cuối\right)}=\dfrac{0,09}{0,25}=0,36\left(M\right)\\ b.n_{HCl}=0,5.0,02=0,01\left(mol\right)\\ n_{H_2SO_4}=0,08.0,2=0,016\left(mol\right)\\ V_{ddsau}=20+80=100\left(ml\right)=0,1\left(l\right)\\ C_{MddH_2SO_4}=\dfrac{0,016}{0,1}=0,16\left(M\right)\\ C_{MddHCl}=\dfrac{0,01}{0,1}=0,1\left(M\right)\)

Bài 2:

\(a.m_{H_2SO_4}=29,4.10\%=2,94\left(g\right)\\ b.n_{H_2SO_4}=\dfrac{2,94}{98}=0,03\left(mol\right)\\ n_{Fe}=\dfrac{0,56}{56}=0,01\left(mol\right)\\ Fe+H_2SO_4\rightarrow FeSO_4+H_2\\ Vì:\dfrac{0,01}{1}< \dfrac{0,03}{1}\Rightarrow H_2SO_4dư\\ n_{H_2SO_4\left(dư\right)}=0,03-0,01=0,02\left(mol\right)\\ m_{H_2SO_4\left(dư\right)}=0,02.98=1,96\left(g\right)\\ n_{H_2}=n_{Fe}=0,01\left(mol\right)\\ \Rightarrow V_{H_2\left(đktc\right)}=0,01.22,4=0,224\left(l\right)\)

a) Ta có: \(n_{NaCl}=\dfrac{5,85}{58,5}=0,1\left(mol\right)\)

\(\Rightarrow C_{M_{NaCl}}=\dfrac{0,1}{0,5}=0,2\left(M\right)=\left[Na^+\right]=\left[Cl^-\right]\)

b) Ta có: \(n_{Ba\left(OH\right)_2}=\dfrac{34,2}{171}=0,2\left(mol\right)\) 

\(\Rightarrow C_{M_{Ba\left(OH\right)_2}}=\dfrac{0,2}{0,5}=0,4\left(M\right)\) \(\Rightarrow\left\{{}\begin{matrix}\left[Ba^{2+}\right]=0,4\left(M\right)\\\left[OH^-\right]=0,8\left(M\right)\end{matrix}\right.\)

c) Ta có: \(n_{H_2SO_4}=0,025\cdot2=0,05\left(mol\right)\)

\(\Rightarrow C_{M_{H_2SO_4}}=\dfrac{0,05}{0,125+0,025}\approx0,33\left(M\right)\) \(\Rightarrow\left\{{}\begin{matrix}\left[H^+\right]=0,66\left(M\right)\\\left[SO_4^{2-}\right]=0,33\left(M\right)\end{matrix}\right.\)

a) \(n_{H_2}=\dfrac{0,8}{2}=0,4\left(mol\right)\)

PTHH: 2A + H₂SO₄ --> A₂SO₄ + H₂

           0,8<-------------------------0,4

=> \(M_A=\dfrac{18,4}{0,8}=23\left(Na\right)\)

b) 

PTHH: 2Na + H₂SO₄ --> Na₂SO₄ + H₂

                          0,4<--------0,4<----0,4

=> \(C_{M\left(ddH_2SO_4\right)}=\dfrac{0,4}{0,5}=0,8M\)

\(C_{M\left(ddNa_2SO_4\right)}=\dfrac{0,4}{0,5}=0,8M\)

n_K = 39/400.100%=9,75%

https://hoc24.vn/hoi-dap/tim-kiem?id=562460&q=t%C3%ADnh%20n%E1%BB%93ng%20%C4%91%E1%BB%99%20ph%E1%BA%A7n%20tr%C4%83m%20c%E1%BB%A7a%20dung%20d%E1%BB%8Bch%20t%E1%BB%8Da%20th%C3%A0nh%20khi%20h%C3%B2a%20tan%20%3A%20%201%2F%2039g%20Kali%20v%C3%A0o%20362g%20n%C6%B0%E1%BB%9Bc%20%202%2F200g%20So3%20v%C3%A0o%201%20l%C3%ADt%20dung%20d%E1%BB%8Bch%20H2SO4%2017%25%20%28D%20%3D%201%2C12%20G%2FML%29

a) Ta có: \(C\%_{NaCl}=\dfrac{60}{60+1250}\cdot100\%\approx4,58\%\)

b) Ta có: \(C_{M_{Na_2CO_3}}=\dfrac{0,5}{0,5}=1\left(M\right)\)

n SO3=\(\dfrac{32}{80}\)=0,4 mol

n BaCl2=2.0,1=0,2 mol

BaCl₂+SO₃+H₂O->BaSO₄+2HCl

0,2---------0,2---------------0,2--------0,4

=>SO₃ dư :

SO₃+H₂O->H₂SO₄

0,2--------------0,2

=>m _BaSO4=0,2.233=46,6g

C%  axit =\(\dfrac{0,4.35,6+0,2.98}{32+100.1,2-46,6}\).100=32,44%

Bài 10:

- Giả sử có 100 gam dd H₂SO₄ 98%

\(m_{H_2SO_4}=\dfrac{100.98}{100}=98\left(g\right)\) => \(n_{H_2SO_4}=\dfrac{98}{98}=1\left(mol\right)\)

\(V_{dd.H_2SO_4.98\%}=\dfrac{100}{1,84}=\dfrac{1250}{23}\left(ml\right)=\dfrac{5}{92}\left(l\right)\)

\(C_{M\left(dd.H_2SO_4.98\%\right)}=\dfrac{1}{\dfrac{5}{92}}=18,4M\)

\(n_{H_2SO_4}=18,4.0,05=0,92\left(mol\right)\)

=> \(m_{H_2SO_4}=0,92.98=90,16\left(g\right)\)

=> \(m_{dd.H_2SO_4.10\%}=\dfrac{90,16.100}{10}=901,6\left(g\right)\)

Bài 11:

a) Do dd sau pư có 3 chát tan với nồng độ % bằng nhau

=> \(m_{Al_2\left(SO_4\right)_3}=m_{ZnSO_4}=m_{H_2SO_4\left(dư\right)}\)

Gọi số mol Al, Zn là a, b (mol)

PTHH: 2Al + 3H₂SO₄ --> Al₂(SO₄)₃ + 3H₂

             a----->1,5a------->0,5a----->1,5a

            Zn + H₂SO₄ --> ZnSO₄ + H₂

             b----->b--------->b----->b

=> \(\left\{{}\begin{matrix}m_{Al_2\left(SO_4\right)_3}=342.0,5a=171a\left(g\right)\\m_{ZnSO_4}=161b\left(g\right)\end{matrix}\right.\)

=> 171a = 161b 

=> \(\dfrac{a}{b}=\dfrac{161}{171}\) (1)

Có: \(\dfrac{m_{Al}}{m_{Zn}}=\dfrac{27.n_{Al}}{65.n_{Zn}}=\dfrac{27}{65}.\dfrac{161}{171}=\dfrac{483}{1235}\)

b) \(n_{H_2}=1,5a+b=\dfrac{11,2}{22,4}=0,5\left(mol\right)\) (2)

(1)(2) => \(\left\{{}\begin{matrix}a=\dfrac{161}{825}\left(mol\right)\\b=\dfrac{57}{275}\left(mol\right)\end{matrix}\right.\)

=> \(x=\dfrac{161}{825}.27+\dfrac{57}{275}.65=\dfrac{5154}{275}\left(g\right)\)

\(m_{H_2SO_4\left(dư\right)}=m_{Al_2\left(SO_4\right)_3}=342.0,5\dfrac{161}{825}=\dfrac{9177}{275}\left(g\right)\)

=> \(m_{H_2SO_4\left(bđ\right)}=98\left(1,5a+b\right)+\dfrac{9177}{275}=\dfrac{22652}{275}\left(g\right)\)

=> \(y=\dfrac{\dfrac{22652}{275}.100}{10}=\dfrac{45304}{55}\left(g\right)\)

\(n_{Fe}=\dfrac{11,2}{56}=0,2mol\)

\(Fe+H_2SO_4\rightarrow FeSO_4+H_2\)

0,2     0,2                0,2       0,2

a)\(V_{H_2}=0,2\cdot22,4=4,48l\)

b)\(C_{M_{H_2SO_4}}=\dfrac{0,2}{0,5}=0,4M\)

c)\(C_{M_{FeSO_4}}=\dfrac{0,2}{0,5}=0,4M\)

\(n_{Fe}=\dfrac{11,2}{56}=0,2\left(mol\right)\) 
pthh : \(Fe+H_2SO_4->FeSO_4+H_2\) 
          0,2                                      0,2
=> \(V_{H_2}=0,2.22,4=4,48\left(L\right)\) 
\(m_{H_2SO_4}=\dfrac{0,5}{22,4}.98\approx2,188\left(g\right)\) 
=> mdd=11,2+2,188=13,388(g) 
C%=\(\dfrac{2,188}{13,388}.100\%=16,3\%\)

a)\(n_{K_2O}=\dfrac{23,5}{94}=0,25mol\)

\(K_2O+H_2O\rightarrow2KOH\)

0,25      0,25       0,5

\(C_M=\dfrac{0,5}{0,5}=1M\)

b)Để trung hòa: \(n_{H^+}=n_{OH^-}=0,5\)

   \(\Rightarrow n_{H_2SO_4}=\dfrac{1}{2}n_{H^+}=0,25mol\)

   \(m_{H_2SO_4}=0,25\cdot98=24,5g\)

   \(\Rightarrow m_{ddHCl}=\dfrac{24,5\cdot100\%}{60\%}=\dfrac{245}{6}g\)

   Thể tích dung dịch:

   \(V=\dfrac{m}{D}=\dfrac{\dfrac{245}{6}}{1,5}\approx27,22ml\)

\(n_{K_2O}=\dfrac{23,5}{94}=0,25\left(mol\right)\\ K_2O+H_2O\rightarrow2KOH\\ n_{KOH}=2.0,25=0,5\left(mol\right)\\ a,C_{M\text{dd}A}=C_{M\text{dd}KOH}=\dfrac{0,5}{0,5}=1\left(M\right)\\ b,2KOH+H_2SO_4\rightarrow K_2SO_4+2H_2O\\ n_{H_2SO_4}=\dfrac{0,5}{2}=0,25\left(mol\right)\\ m_{H_2SO_4}=0,25.98=24,5\left(g\right)\\ m_{\text{dd}H_2SO_4}=\dfrac{24,5.100}{60}=\dfrac{245}{6}\left(g\right)\\ V_{\text{dd}H_2SO_4}=\dfrac{\dfrac{245}{6}}{1,5}=\dfrac{245}{9}\left(ml\right)\approx27,222\left(ml\right)\)